Study of transition-metal monosulphides by photoelectron spectroscopy

J Gopalakrishnan, T Murugesan, M S Hegde and C N R Rao

Abstract

Monosulphides of the first-row transition metals have been studied by X-ray and UV photoelectron spectroscopy. Systematics in the valence bands as well as metal and sulphur core levels across the series have been discussed. Exchange splittings and spin-orbit splittings in these compounds have been examined. CuS is found to show features of both S2- and S22-.

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http://iopscience.iop.org.sci-hub.cc/article/10.1088/0022-3719/12/23/029/meta